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在LCD3D打印中使用高性能聚合物衍生陶.

H Yazdani Sarvestani1, V Karamzadeh1, A Kulkarni1

  • 1Aerospace Manufacturing Technology Centre, National Research Council Canada, Montreal, QC, H3T 2B2, Canada.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|March 17, 2025
PubMed
概括

高强度,轻量化聚合物衍生陶 (PDCs) 使用氧化碳化 (SiOC) 前体和3D打印进行制造. 这种新的方法显著提高了先进应用的机械和热性能.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 陶工程 陶工程 陶工程
  • 增材制造 增材制造 增材制造

背景情况:

  • 聚合物衍生陶 (PDCs) 具有独特的特性,但复杂,高性能结构的制造仍然具有挑战性.
  • 氧化碳 (SiOC) PDC对高温应用具有吸引力.
  • 与传统方法同时实现高强度和复杂几何形状存在局限性.

研究的目的:

  • 为了证明使用LCD vat光聚合 (VPP) 制造具有复杂几何形状的高强度,轻质SiOC PDC的制造.
  • 评估特征厚度和热解温度对材料性能的影响.
  • 开发一种可打印的前体配方,用于先进的陶制造.

主要方法:

  • 使用液晶显示器 (LCD) 容器光聚合 (VPP) 技术,采用氧化碳化 (SiOC) 前体配方.
  • 3D打印复杂的几何形状,如陀螺和随机格子.
  • 使用光学和热重力测量分析 (TGA) 分析了前体特征.
  • 通过微型CT扫描和在800°C和1200°C的热解后的机械测试来评估印刷零件.

主要成果:

  • 一种基于乙烯基甲氧化同聚合物 (VMM-010) 的可打印前体显示出快速固化,低粘度和良好的可打印性.
关键词:
液晶显示器3D打印在高温热解热溶解过程中.机械性能 机械性能 机械性能微观结构的特征描述.聚合物衍生陶材料的使用.

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  • 成功地3D打印了具有高结构完整性和最小空隙的复杂结构.
  • 基于VMM的PDC网格实现了高达9.4 MPa/g cm3的特定压力强度,比控制器提高了50倍.
  • 证明了特殊的高温稳定性,在1500°C下2小时后保持完整性.
  • 组合分析表明自由碳较低,陶阶段形成增强.
  • 结论:

    • VMM-010前体配方非常适合用于高性能SiOC PDCs的LCD3D打印.
    • 这种方法可以使复杂的陶结构具有卓越的机械和热性能,可扩展和可靠地制造.
    • 开发的PDC具有在航空航天,汽车和生物医学领域要求高的应用的巨大潜力.