热水处理对深层液态放射性废物处理处置中的保留的影响
Tolganay B Egorova1, Anna Yu Romanchuk1, Alexander V Egorov1
1Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1/3, 119991 Moscow, Russia. vlasovaie@my.msu.ru.
Environmental science. Processes & impacts
|March 17, 2025
概括
深层沙含水层中 (Pu) 的保留受pH值和二次沉物的影响. 多个注射周期和调节增强了Pu的固定性,而中性pH区域则充当了自然障碍.
科学领域:
- 地质化学 地质化学
- 环境科学 环境科学
- 放射化学 放射化学是指辐射化学.
背景情况:
- 几十年来, (Pu) 酸性液体放射性废物注入了塞维尔斯克地区的深深的沙含水层.
- 了解近场水地化学条件对于预测Pu迁移至关重要.
研究的目的:
- 模拟一个废物注入井的近场条件.
- 在模拟的处置条件下调查Pu的行为,物种和保留机制.
主要方法:
- 废物,排放和偏远的含水层区域的实验室模拟.
- 射线吸收精细结构 (XAFS) 谱学和高分辨率传输电子显微镜 (HRTEM) 用于Pu的特异化.
- 长期漏试验以评估Pu的移动性.
主要成果:
- 在二次沉物上的吸附取决于pH值,控制的保留和移动性.
- 多个注射周期和热水调节稳定了含有Pu的固体,减少了溶解Pu的流动性.
- 在中性pH区域和新鲜的沙子中, (V) 有效地被保留,作为自然屏障.
结论:
- 的pH值是在含水层处置系统中的保留和流动性的关键因素.
- 水热调节和重复注射周期可以增强的固定.
- 自然含水层条件,特别是中性pH区,可以有效地减缓的迁移.
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