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Updated: May 22, 2025

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
11:45

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通过Hydrodearomative [2π + 2σ] Aza-Arenes的循环添加直接获得功能性的2-Azabicyclo[2.1.1]hexanes

Jian Yang1, Bo-Xuan Yao2, Huan-Feng Jiang1

  • 1Key Lab of Functional Molecular Engineering of Guangdong Province in School of Chemistry and Chemical Engineering and State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510641, China.

Angewandte Chemie (International ed. in English)
|March 17, 2025
PubMed
概括

这项研究引入了一种新的Mn/Fe催化剂,用于将aza-arenes转换为3D支架. 这种水解芳香化和循环添加级联有效地创造了功能性的3D2-azabicyclo[2.1.1]hexanes.

关键词:
2 - 亚扎比环[2.1.1] 六化物亚萨-亚伦斯 (aza-arenes) 是一种亚萨-亚伦斯.自行车[1.1.0]酸气体的芳香化方法[2π + 2σ] 循环加法

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