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Updated: May 21, 2025

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Published on: January 30, 2015

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化物诱导的二氧化还原可切换行为二) /四) 情侣

Sebastián Martínez-Vivas1, Macarena Poyatos1, Eduardo Peris1

  • 1Institute of Advanced Materials (INAM), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universitat Jaume I Av. Vicente Sos Baynat s/n Castellón E-12071 Spain poyatosd@uji.es eperis@uji.es.

Chemical science
|March 19, 2025
PubMed
概括

离子可以降低合金复合体中的甲二胺联体,改变它们的反应性. 这一发现为使用 (II) / (IV) 循环的可回氧切换催化剂提供了更简单的替代方案.

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Properties of Transition Metals02:58

Properties of Transition Metals

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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Color in Coordination Complexes
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In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
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