Pt(OH) 协调工程双功能Pt/NiFe LDH-O催化剂,用于强大的水分离
Mengxue Xia1, Feng Chen1, Haojie Liang1
1Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China.
ACS applied materials & interfaces
|March 19, 2025
概括
在铁层双氧化物 (NiFe LDH) 上的的协调工程提高了整体水分裂 (OWS) 的性能. 这种策略优化了金.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 异质催化剂活性通过调节金属活性位点和支持相互作用来增强.
- 层层的双氧化物 (LDH) 支持的 (Pt) 催化剂对整体水分裂 (OWS) 有希望,但缺乏强大的协调,限制了性能.
- 开发稳定和活跃的OWS催化剂对于可再生能源技术至关重要.
研究的目的:
- 通过原子层沉积 (ALD) 来设计 Pt 在 NiFe LDH 上的协调结构,以改进 OWS.
- 研究改变的Pt协调对演化反应 (HER) 和氧演化反应 (OER) 活动的影响.
- 阐明协调结构,电子特性和OWS催化性能之间的关系.
主要方法:
- 原子层沉积 (ALD) 用于精确控制NiFe LDH上的Pt协调.
- 电化学表征以评估 HER,OER 和 OWS 的性能 (过电,稳定性).
- 结构特征和密度函数理论 (DFT) 计算,以了解协调诱导的变化.
主要成果:
- 设计的 Pt/NiFe LDH-O 催化剂对 HER (η10 = 14 mV) 和 OER (η100 = 287 mV) 呈现了较低的超电位.
- 在200多个小时内实现了稳定的OWS活动 (η10 = 1.496V).
- 协调工程降低了Pt-OH,增加了Pt-Pt协调,增强了水解和转移速度决定的步骤.
结论:
- 通过ALD进行协调工程是一种有效的策略,可以提高OWS的Pt/NiFe LDH催化剂性能.
- 改变的Pt协调会影响核形成,生长,电子结构和催化机制.
- 这项工作为LDH支持的催化剂中的结构-活性关系提供了基本的见解.
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