通过国家在接口驱动的分歧来避免考兹曼悖论
Andrew Martin1,2, Jason R Green3,4, Martin Thuo1,2
1Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC, 27695, USA.
Angewandte Chemie (International ed. in English)
|March 19, 2025
概括
考兹曼悖论 (KP) 被核心外粒子 (CSP) 的表面化学物种化挑战. 这种现象阻止了平衡阶段过渡,为深度低温和玻璃形成提供了新的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 非平衡的热力学 热力学
背景情况:
- 考兹曼悖论 (KP) 假定深度超冷的液体可能比晶体固体具有较低的.
- 虽然平衡热力学广泛研究这种灾难,固化是一个远离平衡的过程.
研究的目的:
- 调查远离平衡的过程,特别是核心外粒子 (CSP) 中的表面化学特异如何影响考兹曼悖论.
- 探索在深度低冷过程中避免灾难的可能性.
主要方法:
- 在CSP中凝固的实验和理论分析.
- 不平衡过程的建模,包括表面张量不对称和热力学速度限制.
- 在玻璃形成中分析产量和配置.
主要成果:
- 在CSP中的表面化学特异性扰乱了的产生,阻碍了连续平衡阶段过渡.
- 特异性诱导的表面应力分歧会产生不平衡流,挫败同质核化,并使深度低温成为可能.
- 在热力学速度限制下,考兹曼悖论的修改形式出现,可以通过结合接口状态来避免这种情况.
结论:
- 在CSP中表面化学物种化提供了一种新的机制,以避免考兹曼悖论的灾难.
- 通过考虑界面状态,可以在不违反基本热力学原理的情况下实现深度低温和玻璃形成.
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