在周围压力下,孔化SmNiO2中的散装超导率接近40K
S Lin Er Chow1, Zhaoyang Luo2, A Ariando3
1Department of Physics, Faculty of Science, National University of Singapore, Singapore, Singapore. le.chow@u.nus.edu.
Nature
|March 20, 2025
概括
研究人员在氧化膜中发现高温超导,接近40K. 这一 (Sm-Eu-Ca-Sr) NiO2的突破为探索传统酸盐之外的库珀配对提供了新的可能性.
科学领域:
- 材料科学
- 凝聚物质物理学
- 固态化学
背景情况:
- 在30K附近发现了酸盐 (Ba-La-Cu-O) 的超导性,这促使对更高临界温度 (Tc) 的分层氧化物超导体进行研究.
- 尽管最近发现了酸盐的超导性,但在环境压力下在没有铜的同结构系统中实现超过30K的库珀配对是具有挑战性的.
研究的目的:
- 报告一种新的酸盐系统中的超导性与酸盐具有相同的结构.
- 调查d电子金属氧化物超出铜的高温超导潜力.
主要方法:
- 合成d9-x孔合,后期稀土,无限层氧化 (Sm-Eu-Ca-Sr) NiO2薄膜.
- 通过零电阻状态测量和梅斯纳效应来描述超导性.
- 材料性能分析,包括电阻和残电阻比.
主要成果:
- 在环境压力下观察到接近40K的临界温度 (Tc) 的超导性.
- 证实31K的零阻力状态, 以及梅斯纳效应的证据.
- 合成的薄膜具有极低的电阻 (~0.01 mΩ·cm) 和最小的结构缺陷.
结论:
- 在没有铜的氧化系统中证明了高温超导性.
- 突出了强烈相关的d电子金属氧化物作为高Tc库珀配对的平台的潜力.
- 开辟了探索和理解非传统超导的新途径.
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