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Updated: May 20, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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通过自组合的结晶线圈聚酸-b-聚乙烯 (PP-b-PS) 块共聚物质的度驱动可逆形态转换

Luis Quirós-Montes1, David Presa-Soto1, Raquel de la Campa1

  • 1Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles (IUQOEM), Universidad de Oviedo, Julián Clavería 8, Oviedo, Spain.

Chemistry (Weinheim an der Bergstrasse, Germany)
|March 24, 2025
PubMed
概括

在THF自组装中变化聚-[bis{(trifluoroethoxy) phosphazene]-b-poly{(styrene) 块共聚合物的度会产生多样化的纳米结构. 这种方法控制了PTFEP的结晶性,使先进材料的可调节纳米形态成为可能.

关键词:
区块共聚合物 区块共聚合物结晶驱动自组装 (CDSA) 是一种自组装技术.形态过渡 形态过渡聚化物中的多化物.自动组装的自动组装机

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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water16:24

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Polymer Classification: Crystallinity

Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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