液体与颗粒状硬盘的更热或更冷的晶体之间的非平衡共存
R Maire1, A Plati1, F Smallenburg1
1Université Paris-Saclay, CNRS, Laboratoire de Physique des Solides, 91405 Orsay, France.
The Journal of chemical physics
|March 24, 2025
概括
颗粒状材料可以表现出反直觉的相位共存,热固体与冷液体一起形成. 这是由于固体相中的碰撞频率较低而造成的,这挑战了典型的非平衡系统假设.
科学领域:
- 物理 物理学 物理
- 材料科学 材料科学 材料科学
- 统计力学 统计力学
背景情况:
- 非平衡阶段的共存在自然界中很普遍,但由于缺乏自由能源框架,很难研究.
- 由消散碰撞驱动的颗粒状材料提供了一个模型系统来探索非平衡现象.
- 通常情况下,颗粒系统中的更密集的相因散射增加而变冷,这是非平衡物理学的常见假设.
研究的目的:
- 在非平衡条件下研究颗粒系统的相位行为.
- 挑战共存颗粒相中的温度分布的传统理解.
- 探索碰撞动态在确定相位特性中的作用.
主要方法:
- 使用了简单颗粒模型的数值模拟.
- 分析了包括高密度在内的不同包装分数的系统.
- 扩展动力学理论来预测相位温度.
主要成果:
- 在颗粒系统中证明了热固体阶段和冷液体阶段的共存,这违背了典型的预期.
- 确定了固体相中较低的碰撞频率是这种反直觉温度分布的原因.
- 表明扩展的动力学理论准确地预测相位温度,即使在高包装分数.
结论:
- 碰撞动力学和能量交换是控制颗粒材料相位行为的关键因素.
- 这项研究为非平衡相共存和颗粒系统的基础物理提供了新的见解.
- 这些发现强调了在分析颗粒相位过渡时,除了消散外,考虑碰撞频率的重要性.
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