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Updated: May 20, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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用于马卡西特类型碳二胺的手工造诱导相位过渡

Yuzuki Yamamoto1, Kazuki Kume1, Suzuka Miyazaki1

  • 1Graduate School of Chemical Sciences and Engineering, Hokkaido University, N13 W8, Kita-ku, Sapporo 060-8628, Japan.

Journal of the American Chemical Society
|March 24, 2025
PubMed
概括

高压将马卡西特类型的二化物转化为四角相. 手工研磨也诱导了这种转变,揭示了分子离子化合物的结构变化.

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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