环境友好的氨从水溶液中吸附使用活性木炭和RSM-BBD对参数的优化:可持续的零废弃物方法
Laxmi Deepak Bhatlu M1, Preety Ray2, Parshuram Biswal2
1Department of Chemical Engineering, KPR Institute of Engineering and Technology. Coimbatore, Tamil Nadu 641407, India.
活性马杜卡印加叶木炭有效地从工业废水中去除100%的氨. 这种可持续吸附剂为净化水提供了具有成本效益的解决方案,符合联合国可持续发展目标6.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理技术水处理技术
背景情况:
- 工业废水中的氨污染对水生生态系统,植物和人类健康构成重大风险.
- 有效的氨分离对于环境保护和公共福祉至关重要.
- 吸附被认为是从废水中去除氨的高效方法.
研究的目的:
- 合成和表征活性马杜卡印加叶木炭 (AMLC) 作为吸附剂去除氨.
- 为了优化氨吸附参数使用响应表面方法-盒-Behnken设计 (RSM-BBD).
- 研究氨对AMLC的吸附平衡,动力学和热力学.
主要方法:
- 使用FTIR,XRD,SEM-EDX,TGA,XPS和BET分析合成和描述AMLC.
- 通过RSM-BBD优化吸附参数 (接触时间,吸附剂剂量,pH值,初始度,机速度).
- 使用兰木尔,弗洛因利希和杜宾宁等热量分析吸附平衡.
- 使用伪一阶 (PFO),伪二阶 (PSO) 和粒子内扩散 (IPD) 模型对吸附动力学的建模.
- 热力学研究以确定吸附过程的性质.
主要成果:
- 在AMLC中,AMLC的表面积高达964.252 m2/g.
- 优化的参数实现了100%的最大氨去除效率.
- 兰木尔等温和和PSO动力学最好地描述了吸附平衡和吸附率,分别.
- 吸附过程是内热的,涉及复杂的形成,而不是自发的.
结论:
- 活性马杜卡印加叶木炭是一种高效和可持续的吸附剂,用于从工业废水中去除氨.
- 该研究提供了一种具有成本效益和环保的净水方法,支持联合国可持续发展目标6.
- 利用生物质废弃物进行水处理促进了可持续性,并减少了对化学方法的依赖.
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