用聚氨和环氧化物化学粘合剂将污染物固定在深度毒区
Jinhu Song1, Drew W Johnson2, Jie Huang1
1School of Civil & Environmental Engineering, and Construction Management, The University of Texas at San Antonio, San Antonio, TX, 78249, USA.
Environmental science and pollution research international
|March 25, 2025
概括
使用聚氨和环氧树脂进行现场粘合,有效地固定了深度瓦多斯区 (DVZ) 中的污染物. 这些料显著降低了土壤的多孔性和液压导电性,限制了污染物运输到地下水.
科学领域:
- 环境工程 环境工程
- 地质技术工程 地质技术工程
- 土壤科学 土壤科学
背景情况:
- 由于挖掘的局限性,深度毒区 (DVZ) 在污染物修复方面存在挑战.
- 在现场接提供了一种可行的方法来固定污染物并防止地下水污染.
- 像聚氨和环氧等低粘度树脂可以透到DVZ的低液压导电性土壤中.
研究的目的:
- 评估聚氨,聚氨泡和环氧树脂在降低土壤多孔性,液压导电性和扩散性方面的有效性.
- 根据美国核监管委员会 (NRC) 的标准,评估接材料对浅埋的适用性.
- 调查土壤多孔性和扩散性之间的关系,以及土壤含水量对接性能的影响.
主要方法:
- 模拟污染土壤代表DVZ环境被用于测试.
- 应用了三种基于树脂的接材料 (聚氨,聚氨泡,环氧).
- 在接之前和之后测量了土壤的多孔性,液压导电性和化物扩散性.
- 酸可泄漏性指数是为了评估污染物的固定性而计算的.
主要成果:
- 所有经过凝固的标本都超过了NRC的标准 (酸盐浸性指数> 6) 对于浅埋.
- 观察到孔隙性和扩散性之间的指数关系,与阿奇规则一致.
- 记录的最小孔径为5.1%,最小化物扩散率为2.11 × 10−8 cm2/s.
- 聚氨粘合剂样本显示,随着土壤含水量降低,孔隙性,扩散性和液压导电性降低.
结论:
- 聚氨和环氧接是有效的限制污染物运输在深度剂区内.
- 土土壤符合固体废物处理的监管标准,表明污染物成功固定.
- 该研究为在污染的DVZ环境中实施现场接策略提供了有价值的数据.
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