用于水分离应用的多硫 - 硫化聚乙烯基膜的特性,性能和毒理学评估
Muhammad Usman Yousaf1, Lucca Madeo Cortarelli2, Nerissa I Jebet3
1Department of Chemical and Materials Engineering, Stanley and Karen Pigman College of Engineering, University of Kentucky, Lexington, KY 40506, USA.
Membranes
|March 26, 2025
概括
这项研究开发了聚硫和SPEEK膜,用于去除带电化合物. 化膜减少了有毒溶剂的漏,提高了安全性和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 膜技术在从水中去除带电的小分子方面面临着挑战.
- 聚硫 (PSf) 和硫酸聚乙烯 (SPEEK) 是有前途的膜材料.
- 在膜应用中,最大限度地减少溶剂漏和环境毒性至关重要.
研究的目的:
- 使用NIPS制造和表征PSf和SPEEK膜.
- 为了评估膜在分离带电染料中的性能.
- 通过安全设计 (SbD) 方法评估和减轻溶剂漏和相关的毒性.
主要方法:
- 通过使用NMP溶剂的非溶剂诱导相分离 (NIPS) 进行膜制造.
- 膜的结构,形态和性能特征.
- 使用*Caenorhabditis elegans*进行毒性评估和在不同pH值下火后溶剂液的评估.
主要成果:
- 制造的PSf和SPEEK膜通过尺寸排除和静电相互作用对阴离子染料进行了选择性排斥.
- 化显著降低了被困溶剂的浸出和透毒性,特别是在中性pH下.
- 通过设计 (SbD) 的安全方法在最大限度地减少膜毒性方面表现出有效性.
结论:
- 膜化是一种有效的策略,可以减少溶剂出,提高安全性.
- 在开发高性能,低毒性膜方面,SbD方法至关重要.
- 这些发现有助于更安全,更可持续的基于膜的水处理解决方案.
更多相关视频
09:39Proof-of-Concept for Gas-Entrapping Membranes Derived from Water-Loving SiO2/Si/SiO2 Wafers for Green Desalination
Published on: March 1, 2020
7.3K
10:19Three-Dimensionally Printed Microfluidic Cross-flow System for Ultrafiltration/Nanofiltration Membrane Performance Testing
Published on: February 13, 2016
11.2K
相关概念视频
Dialysis
557
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
557
Potentiometry: Membrane Electrodes
342
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
342
Detergent Purification of Membrane Proteins
5.0K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.0K
