和混合作用对酸盐玻璃的粘弹性行为
Fucheng Wu1,2, Yonggang Huang1,3, Haizheng Tao2
1Institute of Special Glass Fiber & Optoelectronic Functional Materials, China Building Materials Academy, Beijing 100024, China.
Materials (Basel, Switzerland)
|March 27, 2025
概括
这项研究揭示了酸盐玻璃中和氧化物混合如何影响其粘弹性. 观察到一种协同作用的混合效应,与酸盐网络的结构变化有关.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 玻璃科学 玻璃科学
背景情况:
- 粘弹性行为对于各种应用中的材料性能至关重要.
- 了解混合效应是定制玻璃性能的关键.
- 含有氧化物的酸盐玻璃表现出复杂的结构和机械反应.
研究的目的:
- 研究不同Na2O和K2O含量的酸盐玻璃的粘弹性行为和结构演变.
- 为了阐明混合性成分和放松激活能量之间的关系.
- 为玻璃结构和性质的混合效应提供原子级的洞察力.
主要方法:
- 合成具有受控摩尔成分 (70SiO2·(30-x) Na2O·xK2O) 的酸盐玻璃.
- 测量粘弹性特性,包括放松激活能量 (ΔH_Gt).
- 拉曼光谱分析酸盐网络中的结构演变 (Qn物种).
主要成果:
- 在放松激活能量中观察到一个"V"形的趋势,在r = 0.5.5时的最小值.
- 一个协同的混合效应显著影响了粘性弹性特性.
- 拉曼光谱显示结构重组从Q4到Q3再回到Q4随着K2O含量增加.
结论:
- 观察到的粘弹性行为直接与酸盐网络中的动态结构重组有关.
- 混合效应在调节这些玻璃的粘性弹性方面发挥着至关重要的作用.
- 这些发现为优化光纤成像阵列中的涂层材料提供了理论基础.
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