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Updated: May 11, 2026

Microfluidic-based Synthesis of Covalent Organic Frameworks (COFs): A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks (COFs): A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

调节活性中心微环境在基于甲的共价有机框架中,用于增强电催化CO2到CH3OH

Qin Wang1, Junjin Chen1, Houhe Pan1

  • 1Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, 100083, P. R. China.

Advanced materials (Deerfield Beach, Fla.)
|March 28, 2025
PubMed
概括

这项研究开发了一种基于-酸的新型共价有机框架 (PEH-COF) 催化剂. 这种催化剂显著提高了二氧化碳 (CO2) 到甲醇 (CH3OH) 的电催化转化,提高了产量和耐用性.

关键词:
在PCET中,PCET是PCET.协价有机框架 协价有机框架电催化 CO2RRRR 的电催化.甲醇是甲醇中的一种.这是一种phthalocyanine.

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Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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