控制外部球的溶剂重组能量,以打开或关闭人工金属酶的功能

Divyansh Prakash1,2, Suchitra Mitra1,3, Simran Sony1

  • 1Department of Chemistry and Biochemistry, University of Mississippi, University, MS, USA.

Nature communications
|March 29, 2025
PubMed
概括

研究人员设计了人工铜蛋白 (ArCuPs) 来模仿酶功能. 控制这些ArCuP的外部球相互作用,特别是三聚合物 (3SCC) 和四聚合物 (4SCC) 组件,揭示了影响C-H氧化的独特的催化和电子转移特性.

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