热力学建模 砂岩上六甲基氨酸吸附的热力学建模
Munthar Kadhim Abosaoda1,2,3, Bhavesh Kanabar4, Abhinav Kumar5,6
1College of Pharmacy, The Islamic University, Najaf, Iraq.
Scientific reports
|March 29, 2025
概括
这项研究研究了HMTA在砂岩上的吸附,这对于油井水控制至关重要. 吸附是内热的,自发的,遵循兰格穆尔动力学,指导更好的凝治疗.
科学领域:
- 石油工程是石油工程中的一个.
- 储水库工程 储水库工程
- 物理化学 物理化学
背景情况:
- 石油井的过度水产需要在现场进行凝处理.
- 凝成分在水库岩石上的吸附阻碍了有效的凝形成.
- 了解交叉连接器吸附对于优化阻水的策略至关重要.
研究的目的:
- 在砂岩上进行HMTA吸附的新型热力学研究.
- 分析多孔介质中的吸附行为,并在不同的介质中进行比较.
- 为开发石油井水管理改进的凝制剂配方提供见解.
主要方法:
- 在25-80°C的温度下,对石英颗粒进行了批量吸附实验.
- 用兰格穆尔异热模型分析了吸附数据.
- 核心洪水实验使用带有HMTA解决方案的砂岩核心进行.
主要成果:
- 石英上的HMTA吸附遵循兰格穆尔模型,表明单层吸附是由结合驱动的.
- 吸附能力随着温度 (64-93毫克/g岩石) 的增加而增加,这意味着一种内热过程.
- 热力学分析显示了自发吸附 (负的吉布斯自由能量) 与正的和.
结论:
- 砂岩上的HMTA吸附是一种内热和自发的过程,可以通过Langmuir模型进行预测.
- 温度对HMTA吸附能力有积极的影响,这对治疗设计至关重要.
- 在复杂的多孔介质 (核心洪水) 中的吸附显示出比批量实验更低的容量,突出了需要考虑现场条件的需要.
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