关于煤炭氧复合反应的结构变化和自发燃烧特征的研究
Bin Liu1, Xianwei Dong2, Hongwei Mu3
1Xincheng Gold Mine of Shandong Gold Mining Co., LTD., Yantai 261400, China.
ACS omega
|March 31, 2025
概括
了解煤炭 的理解
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 煤炭自发燃烧带来了相当大的风险.
- 防止自发燃烧需要了解煤炭与氧气的反应.
- 氧化过程中的结构和化学变化是关键因素.
研究的目的:
- 研究氧复合物反应过程中煤的结构变化和自燃特性.
- 分析预氧化对煤炭孔隙结构,功能组和气体生产的影响.
- 为防止煤炭自燃提供理论基础.
主要方法:
- 原始和预氧化煤样品的元素分析.
- 表面和内部特征分析 (毛孔分布,功能组).
- 编程加热以分析气体产物 (CO,CO2) 和氧气消耗.
主要成果:
- 煤孔结构从微孔/过渡孔转变为在0-80°C之间的中型/大孔.
- 增加的氧化减少了内部脂肪碳化合物和含氧的功能组.
- 在氧化前过程中,一氧化碳 (CO) 和二氧化碳 (CO2) 的产量随着温度的增加而呈指数级增加.
结论:
- 温度显著改变了煤的孔隙结构和形态.
- 氧化程度会影响内部碳化合物和功能组含量.
- 了解这些变化有助于制定预防煤炭自燃的科学措施.
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