具有对立二极体的Zwitterionic表面活性剂的化受阴离子的不同影响
Laura Mortara1, Matheus P Cortez1, Caroline D Lacerda1
1Instituto de Química, Universidade de São Paulo, São Paulo 05513-970, Brazil.
Langmuir : the ACS journal of surfaces and colloids
|March 31, 2025
概括
带有疏水族群的基离子会影响表面活性剂的化,增加度. 双基表面活性剂的特性受到影响,但不如基基.
科学领域:
- 物理化学 物理化学
- 超分子化学 超分子化学
背景情况:
- 基表面活性剂在各种化学和生物系统中至关重要.
- 了解离子与表面活性剂的相互作用是控制自我组装的关键.
研究的目的:
- 调查水热离子对zwitterionic表面活性剂化的影响.
- 分析阴离子对微粒界面和属性的影响.
主要方法:
- 使用的是异热定位热量计 (ITC).
- 研究的N-多基胆 (DPC) 和N-多基-N,N-二甲基-3-氨基-1-硫酸盐 (DPS) 表面活性剂.
主要成果:
- 具有CF3或C6H5群的热离子增加了对化的热贡献.
- DPS的临界微粒度对阴离子的敏感性比DPC更高.
- 与cationic micelles相比,对zwitterionic micelles的阳离子影响较小.与cationic micelles相比,阳离子对zwitterionic micelles的影响较小.
结论:
- 阳离子上的疏水性群体增强了化热量.
- 兹维特离子表面活性剂中的电荷分布会影响阳离子相互作用的灵敏度.
- 在zwitterionic-anion系统中,双极方向和电荷分布至关重要.
更多相关视频
08:01Synthesis of Monocyte-targeting Peptide Amphiphile Micelles for Imaging of Atherosclerosis
Published on: November 17, 2017
7.3K
11:10Detergent-free Ultrafast Reconstitution of Membrane Proteins into Lipid Bilayers Using Fusogenic Complementary-charged Proteoliposomes.
Published on: April 5, 2018
11.1K
相关概念视频
Intermolecular Forces
56.2K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
56.2K
Induced Electric Dipoles
4.1K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.1K
Aqueous Solutions and Heats of Hydration
14.2K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.2K
Colloids
17.2K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.2K
Solubility
17.1K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.1K
Solvating Effects
7.2K
An understanding of the solvating effect helps rationalize the relation between solvation and acidity of the compound. In addition, this also explains the relative stability of conjugate bases for compounds with different pKa values. This lesson details, in-depth, the principle of solvating effects. The strength of an acid and the stability of its corresponding conjugate base are determined using pKa values. This observed relationship is a consequence of solvation, which is the interaction...
7.2K
