在TMSO-水和SFL-水二元混合物中关联粘度趋势和超快结构动力学
Jiman He1, Min Lin2, Yuting Gao1
1Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education; Shaanxi Key Laboratory of New Concept Sensors and Molecular Materials; School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an, 710119, China.
The journal of physical chemistry letters
|March 31, 2025
概括
四甲基硫氧化物 (TMSO) 和硫 (SFL) 混合物由于结合而表现出不同的粘度. TMSO-水具有强烈的溶解物-水键,影响粘度,而SFL-水相互作用较弱.
科学领域:
- 物理化学 物理化学
- 解决方案化学 解决方案化学
- 频谱学是一种光谱学.
背景情况:
- 结对水溶液的特性有很大的影响.
- 了解溶解物-溶剂相互作用对于预测宏观流体行为至关重要.
研究的目的:
- 为了研究四甲硫氧化物 (TMSO) -水和硫 (SFL) -水二元混合物的键动态.
- 为了将分子层面的相互作用与观察到的粘度趋势相关联.
主要方法:
- 里埃变换红外光谱法 (FTIR) 光谱法
- 超快的红外光谱学超快的红外光谱学.
- 分子动力学 (MD) 模拟
- SCN-作为一个用于重定向动态的局部探测器.
主要成果:
- 由于强烈的溶解物-水键主导水-水相互作用,TMSO-水混合物表现出最大的粘度.
- SFL-水混合物表现出较弱的溶液-水相互作用,导致水动力学与散装粘度脱.
- SCN-探针的重定向动态与对比的粘度趋势直接相关.
结论:
- 溶液-水和水-水结合之间的相互作用决定了这些二元混合物的粘度.
- 在TMSO-水与SFL-水系统中,不同的结模式解释了它们不同的粘度行为.
- 为将分子相互作用与水溶液中的宏观性质联系起来提供了一个框架.
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