导电聚合物涂层控制反应选择性在全铁氧化流电池中的电流反应选择性
Emre B Boz1,2, Ameya Bondre1, Ronald de Bruijne1
1Electrochemical Materials and Systems, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, Eindhoven, 5600 MB, The Netherlands.
Advanced materials (Deerfield Beach, Fla.)
|April 1, 2025
概括
电极上的导电性聚合物涂层改善了水性全铁氧化还原流电池. 聚烯 (PPy) 减少了的演变,而聚3,4-乙烯二氧化 (PEDOT) 提高了电网规模储能效率.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性全铁氧化还原流电池使用丰富的铁和水提供经济的电网规模的能源存储.
- 挑战包括铁/剥离和负电极的演变,限制性能和耐用性.
研究的目的:
- 为了调整全铁氧化还原流电池的负电极反应选择性.
- 研究导电聚合物涂层 (PEDOT/PSS和PPy/PSS) 对电池性能和耐用性的影响.
主要方法:
- 使用聚4-硫酸盐 (PSS) 作为剂,对多3,4-乙烯二氧化 (PEDOT) 和多 (PPy) 的多孔碳电极进行符合性涂层.
- 在模型平台 (旋转盘电极) 和全铁氧化还原流电池中进行电化学研究.
主要成果:
- 无论是PEDOT/PSS还是PPy/PSS涂层,都减少了的演化电流.
- PPy/PSS在高超电位下强烈抑制了的演化.
- PPy/PSS扩大了循环性,并减少了流动细胞中的演变.
- PEDOT/PSS提高了往返效率,可能是通过氧化还原穿机制.
结论:
- 导电聚合物涂层有效地设计了全铁氧化还原流电池中的反应选择性.
- PPy/PSS和PEDOT/PSS为提高电池耐用性和效率提供了明显的好处.
- 这种方法对推进流动电池技术和其他电化学系统具有前景.
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