改进了城市垃圾焚烧的盐热处理工艺,通过液-液相分离来进行飞灰:化物形式过渡和释放行为
Sihua Xu1, Hong Li2, Chenguang Huang1
1State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Journal of environmental management
|April 2, 2025
概括
本研究确定了处理过的焚烧飞灰 (IFA) 中的化物形成,并提出了一种分离化物化的方法. 一个新的工艺使重金属提取和盐分离从IFA在一个步骤的资源利用.
科学领域:
- 环境科学与工程环境科学与工程
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 焚烧飞灰 (IFA) 的盐热处理提取重金属,但留下化物残留物.
- 这些残留物,不溶性和间歇性,阻碍了经过处理的IFA的资源利用.
研究的目的:
- 为了确定IFA在盐处理过程中不溶性化物的形成机制.
- 开发一种方法来从经过处理的IFA中分离化物.
- 为IFA处理,重金属提取和盐分离提出综合工艺.
主要方法:
- 研究了CaCl2在与CaO,SiO2和Al2O3.3一起化物形成中的作用.
- 提议在现场化IFA在融盐的方法,以创建一个液体-液体相进行分离.
- 使用高温处理 (10分钟的1300°C) 来促进融盐的分离.
主要成果:
- 形成了已识别的特定化物化合物,包括Ca12Al14O32Cl2和Ca8Mg(SiO4) 4Cl2.
- 达到大约95%的重量转移到融盐阶段.
- 证明了残留的化物存在于悬浮的盐泡或溶解在化的IFA中.
结论:
- 提出了一种新的融盐辅助的IFA化和玻璃化工艺.
- 这种综合工艺允许同时提取重金属和从IFA分离盐,而无需预处理.
- 开发的方法有助于进一步利用经过处理的IFA的资源.
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