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走向可持续材料:从纤维素生物质到高性能聚合物
Jignesh S Mahajan1,2, Eric R Gottlieb3, Jung Min Kim3
1Department of Materials Science & Engineering, University of Delaware, Newark, Delaware 19716, United States.
概括
作为一种废弃物产品的素可以转化为高性能聚合物和粘合剂. 这项研究开发了用于木质素解构和聚合的创新方法,创造了与以石油为基础的塑料相似的可持续材料.
科学领域:
- 聚合物化学 聚合物化学
- 可持续材料科学科学 可持续材料科学
- 生物质的价值化 生物质的价值化
背景情况:
- 基纤维素生物质提供了芳香化合物的可持续来源,但素往往未得到充分利用.
- 石油化工基聚合物面临与成本和环境影响有关的挑战.
- 宁的反复性和芳香性甲基替代物为材料合成带来了独特的挑战和机会.
研究的目的:
- 开发创新方法,从素分解产品中合成聚合物.
- 为了建立结构-性能-加工关系的素衍生聚合物.
- 探索以素为基础的材料作为石油化学品的可持续替代品的潜力.
主要方法:
- 素衍生甲酸单体的聚合和热力学性质的预测.
- 从富含的生物油开发性能优化的压力敏感粘合剂 (PSAs).
- 在环境条件下强化降解催化解构 (RCD) 的木质素,用于3D打印应用.
- 在环氧树脂中合成可由素衍生的bisguaiacols/bissyringols作为 bisphenol A (BPA) 的替代品.
主要成果:
- 素衍生聚合甲基酸盐的玻璃过渡温度 (Tg) 与聚烯相比或超过.
- 在没有复杂的净化过程中,使用基于的类化合物来制造高性能,无色和无味的PSA.
- 一个加强的RCD工艺将木质素解构成本降低了高达60%,并使3D打印成为可能.
- 素衍生热显示出与BPA/BPF类似物相比较的热和机械性能,由于甲基组,毒性问题减少.
结论:
- 创新的聚合和解构方法释放了素在高性能材料中的潜力.
- 素衍生聚合物为传统石化产品提供可持续和潜在的更安全的替代品.
- 在回收,再循环和商业化方面进行进一步的研究对于推进素衍生材料至关重要.
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