通过多参数传感的发光温度计在YV1-PO4:Eu3+,Er3
Yixuan Ma1, Xiaopeng Zhou1, Jiapeng Wu1
1National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology of National Development and Reform Commission, School of Materials and Energy, Lanzhou University, Lanzhou 730000, China.
Journal of the American Chemical Society
|April 4, 2025
概括
这项研究引入了一种使用YVO4:Eu3+,Er3+的新型发光温度计,用于准确的远程温度传感. 这种材料提供了增强的亮度和广泛的调节温度范围,可进行高达873K的精确测量.
科学领域:
- 材料科学
- 光学传感器
- 纳米技术
背景情况:
- 发光温度计使用温度依赖的发光来进行遥感.
- 添加兰的材料是有效的,但吸收能力较弱,温度敏感性有限.
- 现有的博尔茨曼型温度计的运行范围有限.
研究的目的:
- 开发一种高灵敏度的发光温度计,其亮度提高,温度范围广,可调节.
- 为了克服传统的化物基温度计的局限性.
- 创建一个具有多个温度依赖的发光特性的单一材料.
主要方法:
- 合成的YVO4:Eu3+,Er3+作为发光温度计材料.
- 通过vanadate电荷转移吸收利用敏感的兰坦化物排放.
- 控制 Eu3+ 排放的热灭以调整温度范围.
- 在温度传感应用中研究了微型和纳米晶体形式.
主要成果:
- 在广泛的温度范围 (300-873 K) 中,达到约0.5%/K至5%/K的相对灵敏度 (Sr).
- 证明了一种具有多个温度依赖的发光性质的单一材料:Er3+的LIR和集成的Er3+/Eu3+排放,以及Eu3+排放寿命.
- 展示了在位芯片温度检测,准确度高于1K.
结论:
- YVO4:Eu3+,Er3+作为一个强大的发光温度计,具有卓越的性能.
- 这种材料克服了传统温度计的局限性, 提供了更高的亮度和可调节的灵敏度.
- 展示了实际应用,特别是微电子设备的现场温度监测.
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