外部电压调节在配备铁阳极的微生物电解细胞中从发酵液中回收和维亚尼特:性能和机制
Ting Zhao1, Zhihong Liu2, Zhengtong Guo1
1Department of Water Supply and Drainage, Taiyuan University of Technology, Taiyuan, China.
Journal of environmental management
|April 4, 2025
概括
使用0.8V的铁阳极优化微生物电解细胞 (MEC),最大限度地提高的产量,并实现100%的去除,恢复维亚尼特. 这种电压增强了微生物群落和基因表达,以获得高效的生物能量和资源回收.
科学领域:
- 环境科学 环境科学
- 生物技术是生物技术.
- 电化学 电化学 电化学
背景情况:
- 使用铁阳极的微生物电解细胞 (MEC) 可以增强的生产和从废物生物质中回收vivianite.
- 性能受微生物群落和铁离子水平的影响,而铁离子水平受到应用于电压的影响.
研究的目的:
- 研究不同应用电压 (0.4V,0.6V,0.8V,1.0V) 对MEC中生产和维亚尼特回收的影响.
- 了解驱动这些过程的潜在微生物和遗传机制.
主要方法:
- 带有铁阳极的MEC在不同的电压下运行.
- 测量了的产生,的去除效率和维维亚尼特的纯度.
- 分析了微生物社区组成和功能基因表达.
主要成果:
- 施加0.8V的电压产生了最高的生产率 (11.17 mmol/g COD) 和100%的去除在3天内,与高纯度vivianite (92.7%).
- 0.8V显著改变了微生物群落,增加了电化学活跃的细菌,无氧发酵细菌和不相似的降铁细菌.
- 关键的生产基因被调高,而同类乙生成基因被调低到0.8V.
结论:
- 施加的0.8V电压优化了铁阳极MEC中的协同和回收.
- 这种电压增强了微生物活动和基因表达,这对于有效的生物能源和资源回收至关重要.
- 这些发现为改善MEC在废物回收利用方面的表现提供了洞察力.
相关概念视频
Electrolysis
25.8K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
25.8K
Voltammetry: Overview
332
Voltammetry is an electroanalytical technique in which the current flowing through an electrochemical cell is measured as a function of applied potential, typically under conditions of concentration polarization. The technique provides valuable information about redox-active species, and the current response is plotted as a voltammogram.
A voltammetric cell uses three electrodes: a working electrode, a reference electrode, and an auxiliary electrode. The redox reactions occur in the working...
A voltammetric cell uses three electrodes: a working electrode, a reference electrode, and an auxiliary electrode. The redox reactions occur in the working...
332
Batteries and Fuel Cells
26.8K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.8K
Voltaic/Galvanic Cells
55.4K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
55.4K
Standard Electrode Potentials
42.9K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
42.9K
Voltammograms: Overview
128
Voltammograms are current plots as a function of applied potential, offering insights into electrochemical systems. The shape of a voltammogram depends on how the current is measured and whether convection (heat transfer by fluid movement) is present or absent.
Shapes of Voltammograms
Shapes of Voltammograms
128


