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Updated: May 16, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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从一氧化碳中形成可结晶学表征的终端乙基和三甲基cyclopropanetriolates

Makayla R Luevano1, Cary R Stennett1, Joseph W Ziller1

  • 1Department of Chemistry, University of California, Irvine, California 92697-2025, United States.

Journal of the American Chemical Society
|April 4, 2025
PubMed
概括

研究人员使用重的基酸盐合成了新的稀土金属复合物. 这些复合物与一氧化碳反应,产生前所未有的乙烯复合物和独特的环烯酸三,展示了新的有机金属化学.

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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