硫化零价铁双金属用于地下化蒸汽的被动整治
Clarissa Settimi1, Daniela Zingaretti1, Iason Verginelli1
1Department of Civil Engineering and Computer Science Engineering, University of Rome "Tor Vergata", Via del Politecnico 1, 00133, Rome, Italy.
Environmental pollution (Barking, Essex : 1987)
|April 5, 2025
概括
硫化零价铁 (S-ZVI) 双金属有效降解化溶剂蒸汽,显示出高反应性和稳定性. 这些材料对地下蒸汽处理中的被动缓解系统有前途.
科学领域:
- 环境工程 环境工程
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 化溶剂对环境构成风险.
- 需要有效的蒸汽相处理方法.
- 零价值铁 (ZVI) 是一种已知的反应性材料.
研究的目的:
- 探索硫化零价值铁 (S-ZVI) 双金属用于化溶剂蒸汽处理.
- 评估S-ZVI材料的反应性和稳定性.
- 评估S-ZVI作为水平透反应屏障 (HPRB) 的组成部分.
主要方法:
- 合成S-ZVI双金属使用不同S/ZVI,Cu和Ni比率的磁盘削.
- 在部分和条件下使用三乙烯 (TCE) 进行蒸汽降解批量试验.
- 模拟HPRB条件的TCE扩散柱试验.
- 分析建模用于预测HPRB性能.
主要成果:
- 具有0.05S/ZVI摩尔比率的S-ZVI在18小时内达到高达99%的TCE蒸汽降解.
- 硫化物材料在经过30天的空气老化后保持了反应性.
- TCE降解主要通过β消除发生,产生C3-C6碳化合物.
- 柱体测试显示,在18厘米的HPRB模型中,TCE降解率高达70%.
结论:
- S-ZVI双金属在处理化溶剂蒸汽方面非常有效.
- 与非硫化对应物相比,这些材料提供了增强的稳定性和反应性.
- S-ZVI显示了被动减轻地下化蒸汽排放的显著潜力.
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