对孔隙结构差异的气体吸附分析以及不同形态转化等级的煤炭中的影响因素
Cuixia Wang1, Bohao Zhang2, Jingdan Qiao2
1Xi'an University of Science and Technology, 58 Yanta Middle Road, Xi'an, 710000, Shaanxi, China. 474525043@qq.com.
Scientific reports
|April 6, 2025
概括
煤矿的孔隙结构,包括填充孔和扩散孔,表现出多分体的特征. 更高的煤炭转化增加了填充孔的发展和异质性,影响了气体的储存和运输.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 煤炭矩阵孔隙结构对于气体储存和运输至关重要.
- 了解孔隙异质性是描述煤炭容量的关键.
研究的目的:
- 为了定量描述煤炭矩阵孔隙结构.
- 分析影响毛孔特征的因素.
- 为了研究煤炭孔的多分质性质.
主要方法:
- 低温的液吸附. 低温的液吸附.
- 二氧化碳吸附实验. 二氧化碳吸附实验.
- 多分法理论应用. 多分法理论应用.
主要成果:
- 扩散孔和填充孔都表现出多分体的特征.
- 增加的煤炭转化导致更发达的填充毛孔和更强的异质性.
- 高级煤显示扩散孔异质性;低级煤显示填充孔异质性.
- 填充毛孔异质性与特定表面积和毛孔体积有负相关性.
- 扩散孔异质性与特定的表面积和孔积有正相关.
- 在孔隙异质性和固定的碳含量之间存在"U"形分布.
结论:
- 煤矿的孔隙结构复杂且多重.
- 变形程度显著影响毛孔发育和异质性.
- 特定的表面积,孔腔体积和固定的碳含量是影响孔腔异质性的关键因素.
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