延迟凝酸用于高温碳酸盐储酸化:延迟性和机制研究研究
Weihua Chen1, Pingli Liu2,3, Li Li1
1Engineering Technology Research Institute, PetroChina Southwest Oil and Gas Field Company, Chengdu, Sichuan 610017, China.
ACS omega
|April 7, 2025
概括
一种新型的延迟凝酸,用耐温度聚合物和一个zwitterionic表面活性剂合成,通过超过80%的延迟效率,显著提高了高温碳酸盐储中的刺激.
科学领域:
- 石油工程是石油工程中的一个.
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
背景情况:
- 由于流体损失和有限的透,深层高温碳酸盐储存在重大酸化刺激挑战.
- 现有的凝酸通常缺乏足够的耐温度性,并表现出有限的阻滞效应.
研究的目的:
- 合成一种耐温度凝剂和一种延迟凝酸,以改善碳酸储存器的刺激.
- 评估在高温条件下新型阻滞凝酸的性能和阻滞机制.
主要方法:
- 使用烯胺 (AM),DM-18,DMDAAC和AMPS合成一种耐温度凝剂.
- 作为协同剂,制备了一种具有多基贝 (BS-12) 的延迟凝酸.
- 进行静态减速试验和高温,高压酸岩反应动态实验.
主要成果:
- 阻凝酸在1小时内实现了超过80%的阻效率,超过单个凝酸的性能.
- 在高温下较低的动力反应速率和激活能量表明了卓越的稳定性和有效性.
- SEM和FTIR分析阐明了涉及聚合物网络障碍和吸附膜形成的阻滞机制.
结论:
- 开发的延迟凝酸具有出色的耐温性和卓越的延迟效率,可有效刺激碳酸盐储.
- 凝剂和表面活性剂的协同作用为恶劣的高温环境提供了强大的解决方案.
- 了解减速机制有助于优化对具有挑战性的地质构造进行酸化处理.
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