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Updated: May 15, 2025

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles

Published on: August 22, 2018

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丧的易斯对 (FLP) - 像 (Cyclo) 添加小有机分子到一个稳定的亚甲基化物

Sudip Baguli1, Subham Sarkar1,2, Dibyendu Mallick2

  • 1Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata Mohanpur, Nadia, 741246, India.

Angewandte Chemie (International ed. in English)
|April 7, 2025
PubMed
概括

一种新型的化结合的亚甲基化物 (AY) 激活了各种H-E键和B-B键,显示出不同的反应机制. 这种亚甲基化物也经历了选择性循环添加,突出了其在N-异环合成中的多功能反应性.

关键词:
亚甲基化物 亚甲基化物密度-功能计算密度-功能计算这对丧的易斯夫妇.反应机制的反应机制

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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