开发具有低介电损耗触角的聚胺,通过将聚氧与侧组结合在一起
Riku Takahashi1, Ririka Sawada2, Kan Hatakeyama-Sato1
1Department of Materials Science and Engineering, School of Materials and Chemical Technology, Institute of Science Tokyo, S8-36 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8552, Japan.
Macromolecular rapid communications
|April 7, 2025
概括
对于先进的通信材料来说,新型聚西洛胺聚合物显著降低介电损失 (Df). 这些材料具有低介电常数 (Dk),疏水性和耐热性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 电气工程 电气工程
背景情况:
- 基于西洛的聚合物是下一代通信的有希望的绝缘材料,原因是它们的低介电常数 (Dk),可加工性和机械性能.
- 锡洛干材料的一个主要局限性是它们的高介电损失触角 (Df),阻碍了它们的应用.
研究的目的:
- 设计和合成一种新型的聚西洛胺聚合物,以克服高D的挑战.
- 评估新材料的介电性质,疏水性和热稳定性.
主要方法:
- 通过将聚氧与侧组和聚胺结构结合,合成聚氧胺.
- 合成聚合物薄膜对介电损耗触点 (Df),介电常数 (Dk),疏水性和热性质的表征.
主要成果:
- 与传统的二甲基基聚合物相比,合成的聚西洛胺膜显示出显著降低的Df值.
- 该材料表现出优异的疏水性和高耐热性,体重损失5%的温度超过400°C.
- 含有基的聚氧的刚性被认为有助于改善Df.
结论:
- 开发的具有侧基的聚氧胺提供了低Dk,低Df和出色的疏水性的令人信服的组合.
- 预计这些先进材料将有助于在未来的通信技术中切实应用基于素的绝缘材料.
相关概念视频
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Molecular Weight of Step-Growth Polymers
2.1K
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
2.1K
Polymer Classification: Architecture
2.6K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.6K
Polymer Classification: Stereospecificity
2.3K
Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
2.3K


