甲催化不对称的碳素插入到主要的N相邻的C-H键中,其量超过1000000万

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Updated: May 15, 2025

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Published on: September 8, 2013

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Zong-Rui Li1, Kun Zhan2, Yi-Jie Wang1

  • 1Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Shanghai, PR China.

Nature communications
|April 8, 2025
PubMed
概括

这项研究引入了一种高效的甲催化剂,用于在C-H键中插入不对称的碳,从而产生具有高周转数 (TON) 的奇拉性β-氨基酸. 该方法使可扩展的合成和材料科学中的潜在应用成为可能.

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