将已废弃的离子电池阴极回收到四层层的双氧化物,以实现高效的氧气进化反应
Ronghou Yao1,2, Jin Wu2, Shivam Kansara3
1School of Environment, Henan Normal University, Xinxiang, Henan, 453007, China.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|April 8, 2025
概括
回收使用过的离子电池阴极将它们转化为高效的氧气演化反应电催化剂. 这种新的方法重复使用废物,产生具有高活性和低能源需求的有价值的催化剂.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 环境科学 环境科学
背景情况:
- 使用过的离子电池 (LIB) 由于堆积废物而带来环境和资源挑战.
- 有效回收LIB材料对于可持续性和资源保护至关重要.
研究的目的:
- 开发一种用于再利用废弃LIB阴极材料的新方法.
- 为了将废弃的Li(Co0.8Ni0.1Mn0.1) O2和LiFePO4转化为氧化演化反应 (OER) 电催化剂.
主要方法:
- 采用了简单的浸出和共同沉技术.
- 从回收的阴极材料中合成四分制层双氧化物 (Q-LDHs).
主要成果:
- 优化的Q-LDH-0.1催化剂表现出极好的开放式电源活性.
- 在10 mA cm−2时达到270 mV的低超电位,Tafel斜率为66 mV dec−1.
- 来自Fe,Ni,Co和Mn原子的协同效应通过氧机制增强了催化性能.
结论:
- 提出了一种可行的方法,用于将废弃的LIB阴极材料回收成有效的电催化剂.
- 为开发低成本,高效的双层氧化物 (LDH) 电催化剂提供了洞察力.
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