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相关概念视频

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

158
Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used....
158
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

955
The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
955
NMR Spectrometers: Resolution and Error Correction01:14

NMR Spectrometers: Resolution and Error Correction

598
When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction decay. Fourier transform of an exponential decay yields a Lorentzian peak in the frequency domain. Lorentzian peaks in an NMR spectrum are defined by their amplitude, full width at half maximum, and position, where the peak width is governed by the spin-spin relaxation time alone. In real experiments, however, the applied magnetic field is rendered...
598
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

127
In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
127
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

932
Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
932

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拼接双范围EELS光谱:识别和纠正文物

Alan J Craven1, Bianca Sala2, Donald A MacLaren1

  • 1SUPA School of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ, UK.

Ultramicroscopy
|April 8, 2025
PubMed
概括

电子能量损失光谱 (EELS) 拼接中的工件使用新方法进行了纠正. 这提高了EELS数据的定量分析,即使在系统变化之后.

关键词:
艺术品的纠正 艺术品的纠正直接的电子探测器 电子探测器双双的鱼 双双的鱼电子能量损失光谱学 电子能量损失光谱学

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科学领域:

  • 材料科学 材料科学 材料科学
  • 频谱学是一种光谱学.
  • 电子显微镜电子显微镜

背景情况:

  • 电子能量损失光谱 (EELS) 需要将低和核心损失光谱拼接起来进行全范围分析.
  • 在EELS中的大动态范围导致在拼接点的强度很小,放大了文物效应.

研究的目的:

  • 在EELS数据拼接中调查和纠正文物.
  • 提高EELS分析的定量准确性,特别是在Gatan GIF量子系统中.

主要方法:

  • 确定了三个主要的文物来源:光谱仪的光学偏差,探测器漫游散射和探测器象限响应差异.
  • 开发了测量,量化和纠正这些特定文物的方法.
  • 通过比较校正前后的缩放因子来验证校正.

主要成果:

  • 文物导致缩放因子偏离~15%并取决于样品厚度.
  • 在校正后,缩放因子的差异减少到<0.5%.
  • 证明了在不同时间点和系统配置中对EELS数据进行定量比较的能力.

结论:

  • 开发的方法有效地纠正了EELS数据拼接中的文物.
  • 通过这些纠正,可以准确地对EELS数据进行定量比较.
  • 这些原则适用于各种光谱仪,包括具有直接电子探测器的光谱仪.