从渣中选择性地分离和利用贵金属,制备VOSO电解质4
Zhenghao Wang1, Liang Chen2, Dongmei Luo2
1School of Metallurgy and Environment, Central South University, Changsha, 410083, China; School of Chemical Engineering, Sichuan University, Chengdu, 610065, China.
Journal of environmental management
|April 8, 2025
概括
这项研究提出了一种全面利用渣的新方法,提取铁,,和等贵重金属. 该工艺避免有毒的副产品,并为电池应用生产高纯度材料.
科学领域:
- 金工程 金工程 金工程
- 材料科学 材料科学 材料科学
- 环境化学环境化学
背景情况:
- 传统的渣加工只专注于的提取,导致资源浪费和有毒V (V) 和Cr (VI) 化合物的环境污染.
- 渣含有价值金属,如Fe (II),Mn (II),Cr (III),Ti (IV) 和V (IV),这些金属通常在传统方法中丢失.
研究的目的:
- 开发一种从渣中分离和综合利用多种金属的工艺.
- 通过避免有毒V (V) 和Cr (VI) 的形成,减轻环境污染.
- 制造有价值的材料,包括电池的阴极材料和高纯度的电解质.
主要方法:
- 低温硫酸盐烤制造低价值多金属溶液.
- 氧化酸沉以分离Fe (II) 和Mn (II) 离子,产生LiFe0.5Mn0.5PO4@C阴极材料的前体.
- 复杂的分离,以净化Cr (III) 到Cr (sub) 2 (sub) O (sub) 3 (sub) 并获得符合电池电解质国家标准的高纯度VOSO (sub) 4溶液.
主要成果:
- 成功地从渣中分离和回收Fe,Mn,Cr和V.
- 从Fe和Mn沉物中生产LiFe0.5Mn0.5PO4@C阴极材料.
- 获得97%纯度的Cr2O3和80g/L的VOSO溶液,适用于电池电解质.
- 该工艺实现了全面的金属利用,每1000公斤/小时的渣消耗593千瓦时的能源.
结论:
- 开发的低温硫酸盐烤工艺使渣的有效和环保全面利用成为可能.
- 这种方法将废物转化为有价值的产品,包括先进的电池材料和高纯度的电解质.
- 该研究为渣管理提供了一个可持续的解决方案,解决了资源枯竭和污染问题.
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