缺陷被动化和压力调节通过立的易斯基对高效率的CsPbI3太阳能电池
Huifang Han1,2, Huijing Liu1,2, Yinhui Lv1,2
1New Energy Generation National Engineering Research Center, North China Electric Power University, Beijing, 102206, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|April 9, 2025
概括
一种新的双酸易斯基,2-(2-pyridyl) ethylamine (2-PyEA),有效地使全无机酸 (CsPbI3) 矿膜中的缺陷无活化. 这种被动化增强了结构稳定性,并在各种照明条件下提高了太阳能电池的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 固态化学 固态化学
背景情况:
- 通过低温溶液方法制备的全无机CsPbI3矿薄膜在结晶过程中经常表现出缺陷.
- 单功能的被动器 (硫,,氧) 与Pb2+位点结合较弱,提供有限的缺陷缓解.
- 薄弱的单牙固定容易降解,影响设备的稳定性和性能.
研究的目的:
- 引入一种新型的易斯基双酸基,2-(2-pyridyl) ethylamine (2-PyEA),用于CsPbI3矿的表面被动化.
- 为了提高CsPbI3薄膜的结构稳定性和缺陷被动化.
- 为了提高基于CsPbI3的太阳能电池的功率转换效率 (PCE) 和运行稳定性.
主要方法:
- 基于溶液的CsPbI3矿膜的制备.
- 使用双重易斯基2-PyEA进行表面被动化.
- 结构分析以调查格子扭曲和应力转换.
- 矿太阳能电池 (PSC) 的制造和表征.
主要成果:
- 与单联体相比,2-PyEA表现出更高的协调能力.
- 2-PyEA的双固定诱导了晶格扭曲,将拉力转换为压力,增强了薄膜的稳定性.
- 在标准条件下,太阳能电池的PCE达到21.35% (0.09厘米2) 和17.19% (1.0厘米2).
- 在室内照明下显示了39.95%的显著PCE.
- 在5%相对湿度的环境条件下提高了设备的稳定性.
结论:
- 使用2-PyEA的双酸被动化为稳定CsPbI3矿提供了一个强大的稳定策略.
- 增强的结构完整性和缺陷被动化导致太阳能电池效率的显著提高.
- 开发的被动化方法对高效和稳定的矿太阳能电池充满了希望,特别是用于室内应用.
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