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Updated: May 15, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

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类中间体Geissoschizine的氧化重新排列

Mohamed O Kamileen1,2, Benke Hong1,3, Klaus Gase1

  • 1Department of Natural Product Biosynthesis, Max Planck Institute for Chemical Ecology, D-07745, Jena, Germany.

Angewandte Chemie (International ed. in English)
|April 9, 2025
PubMed
概括

植物使用酶从中介物如19E-geissoschizine中产生多样化的化学结构. 在Catharanthus roseus中,三种P450酶将这种中间体转化为四种不同的化物支架,展示了酶的多功能性.

关键词:
生物合成生物合成酶 是一种酶.格伊索斯奇奇纳 (Geissoschizine) 是一个自然产品是天然产品.植物的P450s是什么

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