化学兴奋剂揭示了有机晶体管中在谷物边界的带状电荷传输
Yating Li1, Mengmeng Niu2, Junpeng Zeng1
1National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering, Key Laboratory of Optoelectronic Devices and Systems with Extreme Performances of MOE and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P. R. China.
Nano letters
|April 10, 2025
概括
有机薄膜晶体管 (OTFT) 具有粒度边界,使用p型兴奋剂进行了改进. 这种兴奋剂策略增强了电荷传输,并减少了有机电子产品的性能差异.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 半导体物理 半导体物理
背景情况:
- 有机半导体为节能,具有成本效益和灵活的电子产品提供了潜力.
- 有机半导体中的颗粒边界 (GB) 显著阻碍了设备的性能和统一性.
- 开发高性能有机电路需要克服GB引发的挑战.
研究的目的:
- 研究单层有机薄膜晶体管 (OTFT) 中GB诱导的陷的被动化.
- 提高电荷传输特性,减少多晶有机薄膜的性能差异.
主要方法:
- 使用p型兴奋剂与有机盐TrTPFB被动化GB诱导的陷.
- 分析了兴奋剂对移动边缘,能量障碍和充电运输机制的影响.
- 描述了设备性能指标,包括移动性,值电压和接触电阻.
主要成果:
- 兴奋剂有效地扩大了移动边缘,屏蔽了GB诱导的能量障碍和库伦散射.
- 电荷运输从多重捕捉和释放 (MTR) 转变为更像带状的行为.
- 实现了超低移动性变化 (1.4%) 和值电压变化 (4.9%).
- 记录了0.6 Ω·cm的创纪录的低接触电阻.
结论:
- 使用TrTPFB的P型兴奋剂有效地使GB诱导的陷在单层OTFT中变得无效.
- 兴奋剂策略使带状电荷传输成为可能,即使存在GBs.
- 化单层多晶薄膜表现出卓越的性能,适用于工业规模的有机电子产品.
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