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埋藏在NiOx基倒置半透明矿太阳能电池中的界面被动化
Bhavna Sharma1, Mohammad Adil Afroz1, Tejasvini Sharma1
1Department of Physics, Indian Institute of Technology Roorkee, Roorkee, Haridwar, Uttarakhand, 247667, India.
Small (Weinheim an der Bergstrasse, Germany)
|April 10, 2025
概括
化酸增强半透明矿太阳能电池 (STPSCs) 通过改善氧化接口,减少能量损失,并提高建筑集成光伏的稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 纳米技术纳米技术
背景情况:
- 半透明矿太阳能电池 (STPSC) 对建筑集成光伏 (BIPV) 是有前途的.
- 用氧化 (NiOx) 倒置的STPSC提供稳定性和透明度,但遭受NiOx/矿差的接口,导致重组和降解.
- 有效的接口工程对于提高STPSC性能和寿命至关重要.
研究的目的:
- 研究化酸对STPSC中NiOx/矿接口的影响.
- 探索酸上的替代如何影响接口特性和设备性能.
- 提高STPSC在BIPV应用中的效率和稳定性.
主要方法:
- 用各种化酸处理的NiOx层的合成和表征 (4-化酸,3,4-二化酸,3,4,5-三化酸).
- 包含修改的NiOx层的倒置STPSC的制造和测试.
- 性能评估包括功率转换效率 (PCE) 和平均可见传输率 (AVT).
- 在受控湿度条件下进行长期稳定性测试.
主要成果:
- 化酸有效地通过去除基团和减轻缺陷状态来使NiOx/矿接口被动化.
- 用4-博酸修改的STPSC实现了冠军PCE15.12%,AVT约为30%.
- 经过1500个小时的存储在30-35%的湿度下,修改后的未封装设备保留了90%的初始PCE,这表明其稳定性优越.
结论:
- 使用化酸的界面被动化是一种可行的策略,可以减少非辐射重组并增强STPSC的稳定性.
- 替代的程度影响了界面修改的有效性.
- 这种方法具有很大的潜力,可以为BIPV应用 (如立面,窗户和天窗) 开发高性能,耐用的STPSC.
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