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Updated: May 14, 2025

Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
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Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications

Published on: June 21, 2017

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没有金属的催化N-甲基化H-硫胺使用CO2

Subir Maji1, Mandira Saha1, Satyaki Sinha1

  • 1Department of Chemical Sciences, Indian Institute of Science Education and Research-Kolkata, Mohanpur 741246, India.

Organic letters
|April 11, 2025
PubMed
概括

这项研究引入了使用二氧化碳 (CO2) 和一个中离子N-异环烯酸 (mNHO) 催化剂的NH-硫胺的无金属催化N-甲基化. 这种高效的方法还可以合成13C标记的N-甲基硫胺.

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Catalysis

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
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