基,无素阻燃剂用于薄,灵活的聚氨人工皮革
Miriam Bader1, Maren Lehmann1, Michael Meyer1
1FILK Freiberg Institute gGmbH, Meißner Ring 1-5, 09599 Freiberg, Germany.
Polymers
|April 12, 2025
概括
阻燃剂 (FRs) 对聚氨 (PUR) 人造皮革至关重要. 一种有机FR显著提高了薄PUR材料的耐火性,为有害的FR提供了更安全的替代品.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 消防安全工程 消防安全工程
背景情况:
- 聚氨 (PUR) 人造皮革广泛用于公共室内,需要有效的阻燃剂 (FR).
- 设计用于散装PUR材料的标准FR通常在薄膜和人工皮革中效果较差.
- 需要无素FRs来取代对环境有害和对健康有害的替代品.
研究的目的:
- 为了评估PUR薄膜和人造皮革中商业上可用的十二种无素FR的有效性.
- 确定最适合用于提高薄PUR材料的耐火性FRs.
- 调查不同FR和添加剂之间的潜在协同效应.
主要方法:
- 在各种度和组合中将十二种无素FR纳入PUR薄膜和人工皮革.
- 使用限制氧指数 (LOI) 测量,圆热量计,水平燃烧测试和热重力测量分析 (TGA) 来评估耐火性.
主要成果:
- 一种有机FR表现出卓越的性能,将LOI从20增加到24.2%,将峰值热释放率降低约30%,并实现自灭行为.
- 酸和三氧化作为这些材料的阻燃剂的效率有限.
- 班托尼特与基于的FR的组合表现出协同效应,降低了可燃性.
结论:
- 商业上可用的无素FRs可以有效地赋予薄型PUR基材料的阻燃性.
- 有机FR特别有望用于耐火人工皮革应用.
- 这项研究通过取代危险的FRs来支持开发更可持续和更安全的材料.
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