以麻油为基础的环氧玻璃制剂,基于具有内在光热自我愈合能力的双动态网络
Yingqing Shao1, Haoxin Zhu1, Kang Chen1
1College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China.
Polymers
|April 12, 2025
概括
这项研究介绍了一种可持续的,以麻油为基础的环氧玻璃制剂 (ASB-ECO),具有双动态网络. 该材料具有出色的机械强度,光热自我愈合,以及电子应用中理想的介电性质.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续材料 可持续材料
背景情况:
- 环氧玻璃仪对于先进的电子产品至关重要,因为它们的机械强度和自我愈合潜力.
- 从生物质中开发可持续的高性能玻璃材料是材料科学中的一个关键挑战.
研究的目的:
- 从麻油中设计一种可持续的环氧玻璃玻璃,具有增强的机械性能和可控制的光热自我愈合.
- 在基于生物质的玻璃制品中研究双动态网络的结构-属性关系.
主要方法:
- 麻油衍生环氧玻璃剂 (ASB-ECO) 的合成,使用胺-胺键和希夫基结合交叉连接剂.
- 描述动态网络行为,包括激活能量 (Ea) 和拓转变温度 (Tv).
- 在可见光下评估光热转换效率 (ηPT) 和自我修复率,同时测量介电性质 (Dk, Df).
主要成果:
- 1.0-ASB-ECO系统表现出动态特征,Ea=37.25kJ/mol和Tv=123.13°C. 这样一来,Ea=37.25kJ/mol和Tv=123.13°C. 这样一来,Ea=37.25kJ/mol和Tv=123.13°C.
- 在可见光下实现了高光热转换效率 (ηPT = 61.42%) 和100%的自我愈合率.
- 证明了有利的介电性质:Dk = 5.54和Df = 0.025在1MHz.
结论:
- 开发的基于生物质的环氧玻璃器为电子材料提供了一个可持续的替代方案.
- 双动态网络设计成功提高了机械性能,并实现了高效的光热自愈.
- ASB-ECO为电子设备中需要耐用性,可靠性和自我修复能力的应用提供了一个有前途的材料.
相关概念视频
Curing of Concrete
1.3K
The hydration of cement takes place within the water-filled capillary pores. However, environmental elements can disrupt this process by evaporating water from the concrete surfaces. Sealed concrete with a water-cement ratio below 0.5 experiences self-desiccation, leading to water loss. The water loss in concrete is mitigated by curing. This technique involves keeping the concrete saturated to maintain the necessary temperature and moisture conditions, to optimally fill the spaces in the cement...
1.3K
Accelerated Curing of Concrete
614
Accelerating concrete curing is achieved by applying heat and additional moisture. This process accelerates the hydration of the cement, resulting in an earlier strength gain in the concrete. Steam curing is a method wherein the concrete products are either transported through a chamber on a conveyor belt or encased in plastic, allowing steam at atmospheric pressure to circulate freely around them. This process begins with a phase of moist curing that typically lasts between 3 to 5 hours, after...
614
Waterproofing and Anti-Bacterial Admixtures in Concrete
302
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
302


