阐明微单元复合推进剂的压力依赖性和燃烧机制
Yuquan Liu1, Dalin Xiang2, Bowen Tao3,4
1State Key Laboratory of Explosion Science and Safety Protection, Beijing Institute of Technology, Beijing, 100081, China. dc516@bit.edu.cn.
Physical chemistry chemical physics : PCCP
|April 14, 2025
概括
固体推进剂的界面控制显著提高了燃烧. 通过优化热量和质量转移以提高性能,AP@Al结构的燃烧速度比Al@AP快2.4倍.
科学领域:
- 燃烧科学和材料工程 燃烧科学和材料工程
- 计算化学和分子动力学模拟.
背景情况:
- 接口控制是提高固体推进剂能量输出和燃烧性能的一个关键策略.
- 像Al@AP和AP@Al这样的微单元结构可以减少燃料和氧化剂之间的热量和质量传递距离.
研究的目的:
- 通过分子动力学模拟来研究Al@AP和AP@Al微单元结构的燃烧行为.
- 在不同压力条件下分析热传递,质量扩散和反应动力学.
- 为了评估层连续性和厚度在AP@Al配置中的影响.
主要方法:
- 进行分子动力学模拟以建模燃烧过程.
- 检查了两个极端压力条件:冷凝相 (恒定体积) 和真空 (变化体积).
- 分析了不同微单元结构的反应动力学,热传递和质量扩散.
主要成果:
- 在凝结相条件下,由于双重反应前线,AP@Al的燃烧速度比Al@AP快2.4倍.
- 由于单一的反应前线,Al@AP表现良好,但消耗较慢.
- 在真空条件下,这两个结构具有相似的能量输出,但AP@Al保持了更快的消耗率,表明压力依赖性较低.
结论:
- 与Al@AP.相比,AP@Al结构显示出更高的燃烧性能和更低的压力依赖性.
- 接口控制策略对于优化固体推进剂燃烧机制至关重要.
- 结果为下一代固体推进剂的合理设计提供了洞察力.
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