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Updated: May 13, 2025

Preparation of Binary and Ternary Deep Eutectic Systems
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揭示了基于糖醇的深度欧性溶剂中的分子相互作用

Letícia A Souza1, Beatriz R de Moraes1, Rafael M de Souza1

  • 1Laboratório de Espectroscopia Molecular, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, São Paulo, 05508000, Brazil. raando@iq.usp.br.

Physical chemistry chemical physics : PCCP
|April 15, 2025
PubMed
概括

阴离子显著影响深层性溶剂 (DES) 的结构和动态. 较强的甘-离子相互作用,特别是与化物相互作用,会影响局部液态动力学和整体溶剂特性.

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The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
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Chemical and Solubility Equilibria

The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if  ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place,...
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Intermolecular Forces and Physical Properties

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Solvents

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The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some external source.
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