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Updated: May 14, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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一个 π-π 相互作用策略,用于向乙烯聚合中的高温稳定 bis ((arylimino) pyridyliron 前催化剂

Muhammad Zada1,2, Qiuyue Zhang2, Qaiser Mahmood3

  • 1Department of Chemistry, Government Postgraduate College Khar, Bajaur 18650, Pakistan.

Dalton transactions (Cambridge, England : 2003)
|April 16, 2025
PubMed
概括

新的含有索基的铁前催化剂显示出增强的热稳定性和在乙烯聚合中的活性. 这些催化剂在高温下保持高聚乙烯分子量,这是由于独特的π-π相互作用.

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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