PFAS吸附在自然水特性上的化物上的干扰
Nathaniel P Sheehan1, Charles A Ponge2, Abe Pankratz3
1Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045, USA.
Chemosphere
|April 16, 2025
概括
化物CP814E (BEA) 能够有效地从水中去除化物和多化物 (PFAS),即使在复杂的矩阵中也是如此. 这种可再生吸附剂在处理PFAS污染的水源方面表现有前途.
科学领域:
- 环境科学 环境科学
- 水处理技术水处理技术
- 材料科学 材料科学 材料科学
背景情况:
- 和多醇基物质 (PFAS) 是广泛存在的人为污染物,具有潜在的健康和环境风险.
- 传统的去除方法,如活性碳和离子交换树脂有局限性.
- 焦石正在成为有前途的吸附剂,具有提高PFAS去除的选择性和再生能力.
研究的目的:
- 评估紫 CP814E (BEA) 在从水中去除 PFAS 的功效.
- 调查各种水矩阵特征对BEA的PFAS吸附性能的影响.
- 评估BEA在PFAS整治中的可再生性和实际应用性.
主要方法:
- 批量吸附实验使用西奥利特CP814E (BEA) 进行.
- 在不同pH值的合成EPA水中测试了PFAS去除,酸 (Na+,Ca2+,Mg2+),酸 (HA),酸 (FA) 和天然有机物质 (NOM).
- 吸附剂的性能在七个热再生周期和真实水样中进行了评估.
主要成果:
- 与超纯水相比,BEA在合成EPA水中证明了更好的PFAS去除.
- Na+,Ca2+和Mg2+离子的存在显著提高了BEA的性能.
- 在6-9的pH范围内,PFAS吸附稳定,并且在1g/L负载下基本不受HA,FA和NOM的影响.
- 在多个再生周期中,BEA 保持了吸附能力,在真水中以 ppt 的水平吸附了 PFOA,PFOS 和 PFHxS.
结论:
- 化物CP814E (BEA) 是一种高效和可再生的吸附剂,用于从水中去除各种PFAS,包括PFOA,PFOS和PFHxS.
- 在存在常见的水矩阵成分和在典型的pH范围内,BEA的性能是稳健的.
- 这项研究强调了BEA作为一种可行的技术,用于在各种水源中进行实际的PFAS整治.
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