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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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Anionic Chain-Growth Polymerization: Overview01:20

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Direct and Indirect Culture Methods for Studying Biodegradable Implant Materials In Vitro
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可降解的聚合物骨粘合剂

Zijian Bao1,2, Ran Yang1,2, Binggang Chen1

  • 1State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

Fundamental research
|April 17, 2025
PubMed
概括
此摘要是机器生成的。

可生物降解的骨粘合剂为金属植入物提供了一个有希望的替代品,用于骨折修复. 本综述探讨了开发这些粘合剂的策略,重点是实现除强度和生物相容性之外的可降解性.

关键词:
可生物降解的材料.骨粘合剂是一种骨粘合剂.骨折 骨折 骨折 骨折 骨折 骨折骨的修复 骨的修复强大的粘附力强.

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科学领域:

  • 整形外科手术 整形外科手术
  • 生物材料科学 生物材料科学
  • 聚合物化学 聚合物化学

背景情况:

  • 压缩性骨折和骨缺陷给骨科带来了重大挑战.
  • 目前的金属植入物可以导致压力屏蔽和骨愈合受损.
  • 可生物降解的骨粘合剂正在成为骨折治疗的优质替代品.

研究的目的:

  • 为制造可生物降解的聚合物骨粘合剂的策略提供全面的概述.
  • 突出理想骨粘合剂的关键性能要求,强调可降解性.
  • 讨论骨粘合剂临床转化方面的挑战和未来方向.

主要方法:

  • 关于可生物降解的聚合物骨粘合剂的现有文献的审查.
  • 对制造策略的分析,平衡可降解性,粘合强度和生物相容性.
  • 讨论 *in vivo* 稳定性和固化要求.

主要成果:

  • 可降解性是骨粘合剂的关键特征,允许骨自然再生,无需进行二次手术.
  • 在保持高粘合强度,生物相容性和*in vivo*稳定性同时实现可降解性是一项挑战.
  • 为了制造具有所需性质的可生物降解聚合物骨粘合剂,存在各种策略.

结论:

  • 可生物降解的聚合物骨粘合剂具有巨大的潜力,可以克服当前骨科固定方法的局限性.
  • 需要进一步的研究来解决临床翻译方面的挑战,并优化粘合性能.
  • 未来的开发应该专注于量身定制的降解速率和增强的*in vivo*功能.