化烯双化物作为无重原子三连体光敏感剂:系统间交叉,电子旋转动力学,以及在光动力学治疗中的应用

Xi Chen1, Ivan V Kurganskii2, Zhiyong Zhuang3,4,5

  • 1State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, 2 Ling Gong Road, Dalian, 116024, P.R. China.

概括

化显著缩短了烯二胺 (PBI) 衍生物的三重状态寿命,影响单一氧气生成. 化PBI二离子具有光催化潜力,因为其长期存在激发状态.

相关概念视频

Cycloaddition Reactions: MO Requirements for Photochemical Activation01:12

Cycloaddition Reactions: MO Requirements for Photochemical Activation

Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.
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Aromatic Hydrocarbon Cations: Structural Overview01:18

Aromatic Hydrocarbon Cations: Structural Overview

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Removing one hydrogen from the intervening CH2 group...
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