探索水力动力学相互作用在球状封闭的干燥体悬浮液中的作用
Mayukh Kundu1, Kritika Kritika2,3, Yashraj M Wani4
1Department of Chemical Engineering, Auburn University, Auburn, Alabama 36849, USA.
The Journal of chemical physics
|April 18, 2025
概括
水力动力相互作用在滴滴干燥过程中显著增强液体-蒸汽界面的颗粒积聚. 动态密度函数理论 (DDFT) 准确地模拟了自由排水系统,但需要对对水力动力相互作用进行改进.
科学领域:
- 体科学是一门关于体的科学.
- 软物质物理学 软物质物理学
- 计算流体动力学的流体动力学.
背景情况:
- 干燥的水滴会产生复杂的环状颗粒分布.
- 水力动力相互作用 (HI) 在不平衡过程中起着至关重要的作用.
- 准确的体系统建模对于理解材料自组装至关重要.
研究的目的:
- 研究干燥滴中的体颗粒分布.
- 分析水力动力相互作用对粒子梯度的影响.
- 将动态密度函数理论 (DDFT) 与基于粒子的模拟进行比较.
主要方法:
- 动态密度函数理论 (DDFT) 的计算.
- 基于粒子的模拟.
- 分析主导导干燥模式的分析.
主要成果:
- 与自由排水的近似相比,对联HI在液体-蒸汽接口上放大了颗粒积累.
- 液滴界面上的溶剂边界条件对粒子分布的影响最小.
- DDFT准确地预测了自由排水水力学中的粒子行为,但在高度的双向HI中失败了.
结论:
- 配对HI对于准确预测干燥滴中的体颗粒行为至关重要.
- 对于复杂的水力动力学场景,当前用于两体相关性的DDFT近似值可能不足.
- 需要进一步开发DDFT以捕捉干燥体系统中对联HI的物理.
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