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Stereoisomerism of Cyclic Compounds02:33

Stereoisomerism of Cyclic Compounds

8.6K
In this lesson, we delve into the role of ring conformation and its stability, which determines the spatial arrangement and, consequently, the molecular symmetry and stereoisomerism of cyclic compounds. 1,2-Dimethylcyclohexane is used as a case study to evaluate the possible number of stereoisomers. Here, given the multiple (n = 2) chiral centers, there are 2n = 4 possible configurations that lack a plane of symmetry, as the ring skeleton exists in a non-planar chair conformation. In addition,...
8.6K
The Contractile Ring02:15

The Contractile Ring

6.1K
Contractile rings are composed of microfilaments and are responsible for separating the daughter cells during cytokinesis. Contractile ring assembly proceeds along with other cell cycle events; however, very few mechanistic details are known about the timing and coordination of the contractile rings with the cell cycle.
A small GTPase, RhoA, controls the function and assembly of the contractile ring. RhoA belongs to the Ras superfamily of proteins. The activation of formins by RhoA promotes...
6.1K
Disubstituted Cyclohexanes: cis-trans Isomerism02:37

Disubstituted Cyclohexanes: cis-trans Isomerism

11.7K
Depending upon the different spatial orientation of the substituents, the disubstituted cycloalkanes exhibit two types of stereoisomers. The cis isomers have the substituents on the same side of the ring, whereas the trans isomers have the substituents on the opposite sides. These stereoisomers exhibit different physical properties and cannot be interconverted without breaking the carbon-carbon bonds.
In cyclohexane, the substituents can occupy different positions generating distinct isomers....
11.7K
Thermal Electrocyclic Reactions: Stereochemistry01:17

Thermal Electrocyclic Reactions: Stereochemistry

1.9K
The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
1.9K
Racemic Mixtures and the Resolution of Enantiomers02:30

Racemic Mixtures and the Resolution of Enantiomers

17.8K
A racemic mixture, or racemate, is an equimolar mixture of enantiomers of a molecule that can be separated using their unique interaction with chiral molecules or media. Racemic mixtures are denoted by the (±)- prefix. This ‘optical rotation descriptor’ applies to the whole solution of a racemic mixture rather than a specific stereoisomer. Enantiomers typically have the same physical and chemical properties. Hence, they are not easily separable. However, enantiomers can exhibit...
17.8K
¹H NMR: Complex Splitting01:13

¹H NMR: Complex Splitting

1.1K
A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
1.1K

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Updated: May 11, 2025

Spatial Separation of Molecular Conformers and Clusters
10:37

Spatial Separation of Molecular Conformers and Clusters

Published on: January 9, 2014

8.8K

在活性环之间具有微分收缩的二进制混合物中的分离.

Emanuel F Teixeira1, Carine P Beatrici1, Heitor C M Fernandes1

  • 1Universidade Federal do Rio Grande do Sul, Instituto de Física, CP 15051, CEP 91501-970 Porto Alegre-Rio Grande do Sul, Brazil.

Physical review letters
|April 18, 2025
PubMed
概括

细胞皮层的收缩驱动细胞形状的变化和分离在多细胞生物. 我们的模型显示差异环收缩导致分离,活动作为有效温度.

科学领域:

  • 细胞生物学 细胞生物学
  • 生物物理学的生物物理.
  • 理论生物学是一个理论生物学.

背景情况:

  • 细胞皮层收缩对于基本的细胞过程如运动,分裂和机械感知至关重要.
  • 细胞之间的差分膜收缩在细胞分离中起着重要作用.
  • 了解驱动细胞分离的物理机制对于发育生物学至关重要.

研究的目的:

  • 模拟由差异性细胞皮层收缩驱动的细胞分离背后的物理机制.
  • 研究活性粒子环动力学与分离现象之间的关系.
  • 将模型预测与现有的集群融合和扩散理论进行比较.

主要方法:

  • 开发一个模拟具有微分收缩的活性粒子环的计算模型.
  • 分析这些活性环的相互作用产生的分离动态.
  • 计算界面衰变指数来描述分离行为.

主要成果:

  • 细胞群的分离直接来自活性粒子环的微分收缩.
  • 环的活性有效地作为影响分离的温度参数起作用.
  • 发现接口衰变指数大约为 λ∼1/3,偏离其他模型的预测.

结论:

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Analyzing Mixing Inhomogeneity in a Microfluidic Device by Microscale Schlieren Technique
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Analyzing Mixing Inhomogeneity in a Microfluidic Device by Microscale Schlieren Technique

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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

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相关实验视频

Last Updated: May 11, 2025

Spatial Separation of Molecular Conformers and Clusters
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Spatial Separation of Molecular Conformers and Clusters

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Analyzing Mixing Inhomogeneity in a Microfluidic Device by Microscale Schlieren Technique
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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  • 差异细胞皮层收缩是推动细胞分离的可行机制.
  • 活环动态为了解细胞分类和组织形态发生提供了一个新的框架.
  • 观察到的接口衰变指数表明,独特的物理原理支配了这个活跃系统中的分离.